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4.1.2 Գ

4.1.2 Գ

( = 0,40786 ). 1064,4, 2880. , . 1 , - 50 2. 0,1 . .

. , , , , 䳺. uSb2 u2P2 .

', , ( 8?10-5 , , 2 1 ), , 䳿. 䳭 1,44 , ul + 1,37 . ٳ ( 20) 19,32 /3, t 1064,43, t 2947; 14,2-10-6 (0-100); 311,48 /(?) [0,744 /(??)]; 132,3 /(?) [0,0316 /(?)] ( 0-100); 2,25-10-8? (2,25?10-6 ?) ( 20); 0,00396 (0-100). 79?103 /2 (79?102 /2), 100-140 /2 (10-14 /2), 30-50%, 90%. ϳ 䳠 270-340 /2 (27-34 /2). 180 /2 (18 /2) ( 4000).

, . :

2u + 62S4 = u2(S4)3 + 2S3 + 2, (4.1)

:

2u + l2 + 21 = 2[u14]. (4.2)

u14 ? 2.

. :

2Au + 3Cl2 = 2AuCl3, (4.3)

2u + F2 = 2uF3 + . (4.4)

u13 ur3, .

u1, ur uI . :

2u1 = 2u + Cl2, (4.5)

:

3ur = ur3 + 2u. (4.6)

, .

() u2Ƿ4N3- .

,

2u13 + 3Snl2 = 3Sn14 +2u. (4.7)

, . .

5d10sl. 1 3 ( , 2-). ( ) 䳺. , 2u+l2 = 2ul.

, [ul4]. NN ( N) 2N[u(N)2]. , 1843 .., 19- (). . u2O . AuCl

u13 = u1 + 12. (4.8)

AuCl3 䳺 2000. 蠠 AuCl3 -

AuCl3 + H2O = H2[AuOCl3]. (4.9)

ul3 - u()3, , - . u23, 220

2u23= 4u + 2. (4.10)

( )

ul3 + 3Sn12 = 3Sn14 + 2u, (4.11) . ʳ (FSO4, 2SO3, H224 .) .

( 198u) , -ﳿ -ﳿ. , , - - , , .



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